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Making sodium from salt

The easiest way to make sodium is to extract it from table salt by high temperature electrolysis. But before we do that, we should have to check the quality of the material. To make high quality sodium it is very important. First of all, we have to crush the salt to make a fine powder, then filtrate it many times to purify as possible. Purification can be done, by dissolving NaCl in distillate water, then pouring the solution through a filtration paper, used in chemistry. After this step the salt must be crystallized by evaporating the water in a dust free environment. (to speed up the crystallization higher temperatures can be used)

So now we have pure NaCl free of dust. If you use chemistry grade NaCl you can leave out the steps above. In order to electrolyse NaCl, it has to be heated up above its melting point. NaCl melts at about 800 degrees Celsius. Most important is, not to overheat the material, as sodium (Na) has a boiling point at around 883 degrees Celsius. It takes a lot of energy to melt salt, but with the right equipment you could do it. When salt is melted DC voltage has to be passed through to separate Chlorine from Sodium. Warning!!!! Chlorine is a very poisonous gas and it can kill you at even low dosages to. Chlorine can be liquefied in a high pressure cylinder, or it can be dissolved in water.

Our first attempt was to melt salt we didn’t purify it or anything. We poured 500g salt on the ground, and started to heat it with AC electric arc using two pieces of SiC electrodes. The intense heat of the arc melted some of the salt. After this we pushed the electrodes into the melt. The intense current flow melted the rest of the salt as you can see in the pictures.

sokezdetvilagos

Our second attempt was to find out, if we can actually produce Sodium. This time we used DC arc with the same electrode configuration to melt salt. We used a 150A full bridge rectifier consisted of three pieces of greatz, each capable up to 50A. We recognised that the bridge have to be cooled to prevent the rectifiers from blowing. The current was around 80A in the melt. Finally we produced Sodium in very small quantities, but it was dirty and reacted very fast with chlorine, as there was no chlorine “chimney”. There was so much trouble to keep the salt in liquid state so we decided to add some CaCl to lower the melting point of the salt to around 500 degrees Celsius.

natrium1

The 150A graetz bridge:

graetzso

 Later on this topic will show you how we make Sodium properly. Until then stay tuned!     

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